Chemistry Net: 03/01/2017 - 04/01/2017

Ionic Radius Periodic Table of the Elements

Ionic Radius Periodic Table of the Elements

Periodic Table with Ionic Radius

 

Ion size plays an important role in determining the structure and stability of ionic solids, the properties of ions in aqueous solution, and the biological effects of ions. As with atoms, it is impossible to define precisely the sizes of ions. Ionic radii are determined from the measured distances between ion centers in ionic compounds. A table of ionic radii is given below.

 

Table 1: Periodic Table with Ionic Radii (Å) of the elements
1 2 3 4 5 6 7

H

1.46

 

         

Li

0.68

Be

0.31

     

 

 

Na

0.98

Mg

0.66

         

K

1.33

Ca

0.99

Sc

0.81

Ti

0.68

 

 

 

 

V

0.59 (+5)

0.63 (+4)

0.74 (+3)

0.88 (+2)

 

 

Cr

0.63 (+3)

0.89 (+2)

Mn

0.80 (+2)

Rb

1.48

Sr

1.13

Y

0.93

Zr

0.80

 

Nb

0.69 (+5)

0.74 (+4)

 

Mo

0.62 (+6)

0.70 (+4)

Tc

 

Cs

1.67

Ba

1.35

La

0.85 (+3)

Hf

0.78

Ta

0.68 (+5)

 

W

0.62 (+6)

0.70 (+4)

 

Re

0.56 (+7)

0.27 (+4)

Fr

˜1.8

Ra

1.43

Ac

 

Th

 

Pa

 

U

 

Np

 

 

Table 1 (continued...)
  8 9 10 11 12
 

 

Fe

0.60 (+3)

0.72 (+2)

 

Co

0.63 (+3)

0.72 (+2)

Ni

0.69 (+2)

 

Cu

0.72 (+2)

0.96 (+1)

Zn

0.74 (+2)

 

Ru

0.68 (+3)

Rh

0.68 (+3)

 

Pd

0.65 (+4)

0.80 (+2)

 

Ag

0.89 (+2)

1.26 (+1)

 

Cd

0.97 (+2)

1.14 (+1)

 

 

Os

0.69 (+6)

0.88 (+4)

Ir

0.68 (+4)

 

Pt

0.65 (+4)

0.80 (+2)

 

Au

0.85 (+2)

1.37 (+1)

 

Hg

1.10 (+2)

1.27 (+1)

 

Table 1 (continued...)
13 14 15 16 17 17

B

0.23 (+3)

 

C

0.15 (+4)

2.60 (-4)

N

1.71 (-3)

O

1.40 (-2)

F

1.33

He

 

Al

0.51 (+3)

 

Si

0.42 (+4)

2.71 (-4)

 

P

0.44 (+3)

2.12(-3)

 

S

0.29 (+6)

1.84 (-2)

Cl

1.81

Ne

 

Ga

0.62 (+3)

 

Ge

0.53 (+4)

0.73 (+2)

 

 

As

0.46 (+5)

0.58 (+3)

2.22 (-3)

 

Se

0.42 (+6)

1.98 (-2)

Br

1.96

Ar

 

In

0.81 (+3)

 

Sn

0.71(+4)

0.93 (+2)

 

 

Sb

0.62 (+5)

0.76 (+3)

2.45 (-3)

 

Te

0.56 (+6)

2.21 (-2)

I

2.20

Kr

 

Tl

0.95 (+3)

 

Pb

0.84 (+4)

1.20 (+2)

Bi

0.96 (+3)

Po

0.67 (+6)

At

˜2.27

Xe

 

 



References

  1. CRC Handbook of Chemistry and Physics, 52nd edition, The Chemical Rubber Co., (1971)
  2. David W. Oxtoby, H.P. Gillis, Alan Campion, “Principles of Modern Chemistry”, Sixth Edition, Thomson Brooks/Cole, 2008
  3. Steven S. Zumdahl, “Chemical Principles”  6th Edition, Houghton Mifflin Company, 2009

Key Terms

ionic radius, , ionic size, ionic radius table,


Ionization Energy Periodic Table of the Elements

Ionization Energies Periodic Table of the Elements

Periodic Table with Ionization Energies

 

The ionization energy of an atom or ion is the minimum energy required to remove an electron from the ground state of the isolated gaseous atom or ion. The first ionization energy, I1, is the energy needed to remove the first electron from a neutral atom.

M (g) —› M+ (g) + e-

It is related to the atom's electronegativity and electron affinity. Tables of electronegativities and electron affinities were given in the posts entitled "Electronegativities Periodic Table of the Elements" and "Electron Affinities Periodic Table of the Elements". A table of first ionization energies of the elements is given below.

 

Table 1: Periodic Table with Ionization Energies (kJ/mol) of gaseous atoms of the elements
1 2 3 4 5 6 7 8 9 10 11 12

H

1312.00

 

                   

Li

520.2

Be

899.4

     

 

 

     

 

 

Na

495.8

Mg

737.7

                   

K

418.8

Ca

589.8

Sc

631

Ti

658

V

650

Cr

652.8

Mn

717.4

Fe

759.3

Co

758

Ni

736.7

Cu

745.4

Zn

906.4

Rb

403.0

Sr

549.5

Y

616

Zr

660

Nb

664

Mo

684.9

Tc

702

Ru

711

Rh

720

Pd

805

Ag

731.0

Cd

867.7

Cs

375.7

Ba

502.9

La

523.5

Hf

654

Ta

761

W

770

Re

760

Os

840

Ir

880

Pt

868

Au

890.1

Hg

1007.0

Fr

˜400

Ra

 

Ac

 

Th

 

Pa

 

U

 

Np

 

         

 

Table 1 (continued...)
13 14 15 16 17 17

B

800.6

C

1086.4

N

1402.3

O

140.98

F

1681.0

He

2372.3

Al

577.6

Si

786.4

P

1011.7

S

200.41

Cl

1251.1

Ne

2080.6

Ga

578.8

Ge

762.2

As

947

Se

194.97

Br

1139.9

Ar

1520.5

In

558.3

Sn

708.6

Sb

833.7

Te

190.15

I

1008.4

Kr

1350.7

Tl

589.3

Pb

715.5

Bi

703.3

Po

˜180

At

˜930

Xe

1170.4

 



References

  1. CRC Handbook of Chemistry and Physics, 52nd edition, The Chemical Rubber Co., (1971)
  2. David W. Oxtoby, H.P. Gillis, Alan Campion, “Principles of Modern Chemistry”, Sixth Edition, Thomson Brooks/Cole, 2008
  3. Steven S. Zumdahl, “Chemical Principles”  6th Edition, Houghton Mifflin Company, 2009

Key Terms

electron affinities, electronegativity difference, electron affinity, ionization energy,


Electron Affinities Periodic Table of the Elements

Electron affinities Periodic Table of the Elements

Periodic Table with Electron Affinities

 

The electron affinity of an atom is the energy released when an electron is added to it. It is related to the atom's ionization energy and electronegativity. The basic difference between ionization energy and electron affinity is that ionization energy measures the ease with which an atom loses an electron, while electron affinity measures the ease with which an atom gains an electron.

 

Table 1: Periodic Table with Electron Affinities (kJ/mol) of gaseous atoms of the elements
1 2 3 4 5 6 7 8 9 10 11 12

H

72.77

 

                   

Li

59.63

Be

< 0

     

 

 

     

 

 

Na

52.87

Mg

< 0

                   

K

48.38

Ca

2.0

Sc

18.1

Ti

7.6

V

50.7

Cr

64.3

Mn

< 0

Fe

15.7

Co

63.8

Ni

111.5

Cu

118.5

Zn

< 0

Rb

46.88

Sr

4.6

Y

29.6

Zr

41.1

Nb

86.2

Mo

72.0

Tc

˜53

Ru

˜100

Rh

110

Pd

51.8

Ag

125.6

Cd

< 0

Cs

45.50

Ba

13.95

La

˜50

Hf

˜0

Ta

31.1

W

78.6

Re

˜14

Os

˜106

Ir

151

Pt

205.1

Au

222.7

Hg

< 0

Fr

44.00

Ra

> 0

Ac

1.1

Th

1.3

Pa

 

U

 

Np

 

         

 

Table 1 (continued...)
13 14 15 16 17

B

26.7

C

121.85

N

-7

O

140.98

F

328.0

Al

42.6

Si

133.6

P

72.03

S

200.41

Cl

349.0

Ga

29

Ge

˜120

As

˜80

Se

194.97

Br

324.7

In

29

Sn

˜120

Sb

103

Te

190.15

I

295.2

Tl

˜20

Pb

35.1

Bi

91.3

Po

˜180

At

˜270

         

 



References

  1. CRC Handbook of Chemistry and Physics, 52nd edition, The Chemical Rubber Co., (1971)
  2. David W. Oxtoby, H.P. Gillis, Alan Campion, “Principles of Modern Chemistry”, Sixth Edition, Thomson Brooks/Cole, 2008
  3. Steven S. Zumdahl, “Chemical Principles”  6th Edition, Houghton Mifflin Company, 2009

Key Terms

electron affinities, electronegativity difference, electron affinity, ionization energy,


Standard Enthalpies of Formation of Organic Compounds

Standard Enthalpies of Formation of selected organic compounds

Standard Enthalpies of Formation of Organic Compounds

 

The standard enthalpy of formation ΔΗ°f of a substance is the change in enthalpy for the reaction that forms 1 mol of the substance from its elements with all reactants and products at 1 atm pressure and usually 298.15 K. For any element in its most stable state at 298 K and 1 atm pressure, ΔΗ°f = 0. Standard enthalpies of formation of inorganic compounds were given in a previous post.

 

Table 1: Standard Molar Enthalpies of Formation ΔΗ°f at 25 °C (298.15K)

Substance Formula ΔΗ°f 
Acetylene C2H2(g) 226.7
Acetic Acid CH3COOH(l) -484.0
Acetaldehyde CH3CHO(g) -166.0
Benzene C6H6(l) 49.0
Carbon Tetrachloride CCl4(l) -135.0
Diamond C(s) 1.88
Ethane C2H6(g) -84.68
Ethanol C2H5OH(l) -277.7
Ethylene C2H4(g) 52.30
Ethylene Oxide C2H4O(g) -53.00
Formaldehyde HCOOH(g) -116
Formic Acid C2H4(g) -363
Glucose C6H12O6(s) -1273
Methane CH4(g) -74.80
Methanol CH3OH(g) -201
Propane C3H8(g) -103.85
Propene C3H6(g) 20.90
Sucrose C12H22O11(s) -2221

 



References

  1. CRC Handbook of Chemistry and Physics, 52nd edition, The Chemical Rubber Co., (1971)
  2. David W. Oxtoby, H.P. Gillis, Alan Campion, “Principles of Modern Chemistry”, Sixth Edition, Thomson Brooks/Cole, 2008
  3. Steven S. Zumdahl, “Chemical Principles”  6th Edition, Houghton Mifflin Company, 2009

Key Terms

standard enthalpies of formation, molar enthalpies of formation, table of standard enthalpies of formation ,


Electronegativities Periodic Table of the Elements

Electronegativities Periodic Table of the Elements

Periodic Table with Electronegativities

 

Electronegativity is defined as the ability of an atom in a molecule to attract electrons to itself. The electronegativity of an atom in a molecule is related to the atom's ionization energy and electron affinity, which are properties of isolated atoms. An atom with a high ionization energy and with a very negative electron affinity both resists having its electrons attracted away and attracts electrons from other atoms. It is highly electronegative.

Linus Pauling developed the first and most widely used electronegativity scale which is based on thermochemical data (Table 1). There is generally an increase in electronegativity from left to right across a row of the periodic table. Electonegativity decreases -with a few exceptions like the transition metals - with increasing atomic number or from up to down in a row of the periodic table.

Electronegativities are used to estimate whether a given bond is covalent, polar covalent, or ionic.

 

Table 1: Periodic Table with Electronegativities
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17

H

2.1

 

                             

Li

1.0

Be

1.5

     

 

 

     

 

 

B

2.0

C

2.5

N

3.0

O

3.5

F

4.0

Na

0.9

Mg

1.2

                   

Al

1.5

Si

1.8

P

2.1

S

2.5

Cl

3.0

K

0.8

Ca

1.0

Sc

1.3

Ti

1.5

V

1.6

Cr

1.6

Mn

1.5

Fe

1.8

Co

1.9

Ni

1.9

Cu

1.9

Zn

1.6

Ga

1.6

Ge

1.8

As

2.0

Se

2.4

Br

2.8

Rb

0.8

Sr

1.0

Y

1.2

Zr

1.4

Nb

1.6

Mo

1.8

Tc

1.9

Ru

2.2

Rh

2.2

Pd

2.2

Ag

1.9

Cd

1.7

In

1.7

Sn

1.8

Sb

1.9

Te

2.1

I

2.5

Cs

0.7

Ba

0.9

La

1.0

Hf

1.3

Ta

1.5

W

1.7

Re

1.9

Os

2.2

Ir

2.2

Pt

2.2

Au

2.4

Hg

1.9

Tl

1.8

Pb

1.9

Bi

1.9

Po

2.0

At

2.2

Fr

0.7

Ra

0.9

Ac

1.1

Th

1.3

Pa

1.4

U

1.4

Np

1.4

                   

 

 


References

  1. CRC Handbook of Chemistry and Physics, 52nd edition, The Chemical Rubber Co., (1971)
  2. David W. Oxtoby, H.P. Gillis, Alan Campion, “Principles of Modern Chemistry”, Sixth Edition, Thomson Brooks/Cole, 2008
  3. Steven S. Zumdahl, “Chemical Principles”  6th Edition, Houghton Mifflin Company, 2009

Key Terms

electronegativity, electronegativity difference, electron affinity, ionization energy, Pauling,