Subject Index

A

acid, strong

acid, strong, pH

acid, strong, solved examples

acid, weak

acid –base indicators

acid – base strength

alumina

alumina, LC, HPLC

analytical chemistry

aprotic solvents

atomic absorption spectrometry (AAS)

atomic absorption spectrometry, advantages & disadvantages

atomic absorption spectrometry, applications

atomic absorption spectrometry, history

atomic absorption spectrometry, quantitative analysis

autoionization, of H₂O

B

band broadening

band fronting

bonded phase columns

bond, covalent

bond, ionic

bonded phases

C

calibration curve, AAS

calibration, 1-point / 2-point / 3-point

calibration, pH-meter

carbocations, 1,2-hydrogen shift

carbocations, 1,2-methyl shift

carbocations, formation

carbocations, reactions

carbocations, rearrangements

carbocations, rearrangements and change in ring size

carbocations, stability

cation exchange resin

characteristic concentration (sensitivity), AAS

charge balance equation

chemical bond

chromatographic resolution

column capacity

column diameter

column efficiency

column length

column packing

column theory

column, LC, HPLC

covalent bond

D

Dalton’s law

detection limit

dissociation constant, k_a, k_b

dissociation reaction

Dixon’s Q-test

E

electrons, valence

elution, order

equilibrium chemical

equilibrium constant, k

end-capping reaction

extra column effects

F

formal charge

frequency distributions

G

gel filtration (GFC), LC

gel permeation (GPC), LC

gradient elution

graphite furnace

Grubbs test

H

Henry’s law

histogram

HPLC, components and functions

hydrogen, -1, -2, shifts

hydronium ion,  H₃O⁺

I

ideal gas law

injector, LC, HPLC

ion exchange , IEC

ion exchange, cation exchange resin

ion product k_w

J

K

L

Lewis dot structure of the dichromate anion, Cr₂O₇^-2

Lewis structure

Lewis structures, simple method for drawing

Lewis structure of carbon dioxide, CO₂

Lewis structure of the carbonate ion, CO₃^-2

Lewis structure of the cyanate ion, NCO^-

Lewis structure of hydrogen cyanide, HCN

Lewis structure of IO₃^-

Lewis structure of the NO₂⁺

Lewis structure of NOCl

Lewis structure of nitrogen dioxide, NO₂

Lewis structure of ozone, O₃

Lewis structures, octet rule

Lewis structure of phosgene, COCl₂

Lewis structure of sulfur trioxide, SO₃

Lewis symbols

Lewis theory

liquid chromatography

liquid liquid chromatography, LLC

liquid solid chromatography, LSC

liquid solid chromatography, mechanism

M

maintenance, LC, HPLC

mass balance equation

mechanism of adsorption

mobile phase, normal phase chromatography

molecular size, LC separation

mole fraction

N

normal phase chromatography

normal Q-Q chart plots

 normal phase liquid chromatography, disadvantages

O

octet rule

outlier

outliers, detection

ozone, O₃

P

partial pressure

pH meter

peak shoulders

peak tailing

pinacol rearrangement

polarity of a compound, LC mode

polarity, column, LC

polarity, mobile phase, LC

polarity, separation, LC

protic solvents

pump, HPLC, LC

Q

qualitative analysis, LC, HPLC

R

racemic mixture

rearrangement, pinacol

resolution, chromatography

resonance structure

retention volume

reversed phase

S

sample overload

selectivity 

sensitivity (characteristic concentration), AAS

separation mode, LC, HPLC

shifts hydrogen, 1-, 2-

silica

silica, LLC

skewed distribution

S_N2 reaction, kinetic evidence

S_N2 reaction, mechanism

S_N2 reaction, stereochemical evidence

solvent, rate of S_N2 & S_N1

solvent effects, S_N2, S_N1

solvent strength

standard addition

standard deviation, 

stationary phase, selection, LC

steric exclusion, mechanicm

steric exclusion, polymer characterization

steric exclusion, SEC

substitution nucleophilic bimolecular, S_N2

substitution nucleophilic bimolecular, S_N2, Walden inversion

substitution nucleophilic unimolecular, S_N1

substitution nucleophilic, alcohols

substitution nucleophilic, alkyl bromides

T

theoretical plate

troubleshooting, LC, HPLC

U

V

valence electrons

W

Walden inversion

X

Y

Z

z-score