An Easy Method for Constructing Dot Structures - Example: The Dicarbide ion C2-2
A simple procedure for writing Lewis structures is given in a previous
article entitled “Lewis
Structures and the Octet Rule”.
Several worked examples relevant to this procedure were given in previous posts please see the Sitemap - Table of Contents (Lewis Electron Dot Structures).
Let us consider the case of C2-2.
Step 1: Connect the atoms with
single bonds.
Fig. 1: Connecting the atoms of C2-2 with single bonds (Step 1 of the method) |
Step 2: Calculate the # of
electrons in π bonds (multiple bonds) using formula (1):
Where n in this
case is 2 since C2-2
consists of 2 atoms.
Calculate the number of the valence electons (V) of C2-2 :
Where V = 2*4 – (-2) = 10
Where V = 2*4 – (-2) = 10
Therefore, P = 6n
+ 2 – V = 6 *2 + 2 – 10 = 4 Therefore, there are either 2 double bonds or 1
triple bond.
The structure in
Figure 1 cannot have 2 double bonds. The only possibility is 1 triple bond.
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